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sodium amalgam : ウィキペディア英語版 | sodium amalgam Sodium amalgam, commonly denoted Na(Hg), is an alloy of mercury and sodium. The term amalgam is used for alloys, intermetallic compounds, and solutions (both solid solutions and liquid solutions) involving mercury as a major component. Sodium amalgam is often used in reactions as strong reducing agents with better handling properties compared to solid sodium. They are less dangerously reactive toward water and in fact are often used as an aqueous suspension. ==Structure and compositions== No particular formula is assigned to "sodium amalgam." Na5Hg8 and Na3Hg are well defined compounds. In sodium amalgams, the Hg-Hg distances are expanded to around 5 Å vs. about 3 Å for mercury itself. Usually amalgams are classified on the weight percent of sodium. Amalgams with 2% Na are solids at room temperature, whereas some more dilute amalgams remain liquid.〔Keith R. Buszek "Sodium Amalgam" in Encyclopedia of Reagents for Organic Synthesis, 2001, John Wiley. 〕
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